PRODUCTION OF CARBONACEOUS MATERIALS USING COAL TAR RESIN AND INVESTIGATION OF THEIR SURFACE PROPERTIES

Abstract

The traditional technological process for creating highly porous materials from carbonaceous raw materials involves two stages of thermal treatment: carbonization (pyrolysis) and activation (gasification), aimed at forming a porous structure capable of adsorption. Combining both stages into a single process with chemical activation allows for efficient raw material utilization and control of the material's porous structure at different levels, providing the ability to customize its characteristics. The choice of a chemical activator depends on the type of raw material and the required characteristics of porous carbon materials. In this study, it is established that the analysis of surface properties of highly porous carbon materials synthesized from coal tar pitch, obtained by distillation of coal tar resin from JSC "Shubarkolkomir," confirms the outstanding operational characteristics of this material. The application of a combined process of carbonization and activation of coal tar pitch at an optimal temperature in an inert atmosphere leads to the formation of porous carbon materials with a high specific surface area: 561 (traditional method), 789 (chemical activation), and 881 m²/g (templating method), as well as a pore volume of 0.30; 0.40; and 0.48 cm³/g, respectively. This work not only expands the technological methods of obtaining carbon materials from coal tar resin but also underscores their potential for improving soil structure and increasing the efficiency of agricultural production.