INVESTIGATION OF SORPTION PROPERTIES OF A DISPERSED SYSTEM OBTAINED FROM NATURAL BIOPOLYMERS

Authors

  • A. H. ZHAKINA Institute of Organic Synthesis and Coal Chemistry the Republic of Kazakhstan
  • A. T. TAKIBAYEVA Karaganda State Technical University
  • A. N. AKZHOLTAI Karaganda State Technical University
  • A. ALZHANKYZY Karaganda State Technical University
  • S.A. Semenova Federal Research Center of Coal and Coal chemistry, Siberian Branch, Russian Academy of Sciences

Keywords:

dispersion system, gelatin, sodium humate, sorption, sorbent, cleaning

Abstract

In this paper, the regularities of the processes of structure formation of mixed aqueous solutions of sodium humate with a natural polymer – gelatin are studied and their sorption properties are studied. The choice of gelatin as a natural polymer is due to its high gel-forming properties, the presence of functional groups that contribute to the formation of intermolecular bonds, as well as industrial availability. To obtain a dispersed system, a method of mixing water solutions of the initial components is used, in which the self-organizing forces of the initial polymer components are manifested. The modifying influence of humate, pH of the medium and time on the process of system structure formation is studied. It is assumed that the stability of mixtures is related to the structure of the structure of humate and gelatin. That when combined, various forces of intermacromolecular interaction come to the fore and self-organizing capabilities of polymers are realized, which lead to a significant improvement in the properties of the original polymers. It is noted that the directed modification by combining polymers gives almost limitless possibilities for their application in various fields, primarily in wastewater treatment. Sorption properties of absorption of copper, nickel and lead ions from aqueous solutions of their salts were studied for the obtained mixtures of different compositions. The influence of the ratio of initial components on sorption is estimated. It was found that the sorption activity of polymer-polymer complexes increases with the increase in the humate mixture. The effectiveness of their application in sorption processes is shown and they are recommended as sorbents for wastewater treatment from heavy metal ions.

References

[1] Kuleznev V.N. Chemistry and physics of polymers. M.: Kolos, 2007. 367 p.

[2] Khrustaleva G.K. The geological aspects of the production of humic preparations fromcoals // Review. information. M.: LLC "Geoinformtsentr", 2003. 50 p.

[3] Zhakina A.H., Bektemisova A.U., Satymbaeva A.S., Akkulova Z.G., Zholbolsynova A.S. Investigation of gelatin-HUMATE sorbents // Proceedings of the International scientific and practical conference. "Clean water-2009". Kemerovo, 2009. P. 404-408.

[4] Golovin G.S., Lesnikova E.B., Artemova N.I., Lukicheva V.P. Use of humic acids of solid combustible fossils // Chemistry of solid fuel. 2004. No 6. P. 43-49.

[5] Reshetnyak E.A., Nikitina N. and etc. Protolytic and complexing properties of indicators in the gelatinous gel medium // Bulletin of Kharkov national University. Chemistry, 2005. Vol. 13 (36 № 669). P. 48-52.

[6] Litmanovich O.E., Papisov I.M. The influence of the length of the macromolecules on the particle size of the metal recovered in the polymer solution // High molecular weight compounds. 1999. Vol. A41, No. 11. P. 1824-1830.

[7] Sutyagin V.M., Bondaletov L.I. Chemistry and physics of polymers: textbook. Tomsk, 2003. 208 p.

[8] Bataev A.A. Composite materials: structure, preparation, application. Novosibirsk: NSTU, 2002. 384 p.

[9] Troitsky A.B., Solodovnik A.V., Pisky V.A. Structured disperse systems. Belgorod, 2005. 453 p.

[10] Mashkov Yu.K. Polymer composite materials in tribotechnics. M.: LLC "Nedra" – business Center, 2004. 262 p.

[11] Vlasov S.V. Fundamentals of plastics processing technology: textbook for universities. Cheboksary: SUE IPK Chuvashia, 2004. 596 p.

[12] Patent № 17759. Kazakhstan. Polymer composition for obtaining film material / Zhubanov B. A., Kravtsova V. D., Iskakov R. M., Sarieva R. B., Abilova M. B. Published 08.12.2005.

[13] Bubnova M.L., A. I. Efremova et al. Relaxation properties of physical grids formed by hydrogen bonds // High molecular weight compounds. Ser.A. 2002. Vol. 44, No. 6. P. 967-972

[14] Melnik O.P., Mank V.V. The role of water in the processes of structure formation of biopolymers // Question to chemists and chemistry technologies. 2010. No. 2. P. 1-17.

[15] Shandryuk G.A., Koval M.V. et al. Hydrogen bonding as a method of modification of liquid crystal polymers and other substances // High molecular weight compounds. Ser.A. 2002. Vol. 44, No. 3. P. 434-442.

[16] Saldadze K.M., Kopylova–Valova V.G. Complexing ion-exchange resins. M.: Chemistry, 1980. 336 p.

[17] Patlazhan S.A. Diagrams of the state of polymer solutions forming thermo-reversible gels // High molecular compounds, A-B. 1998. Vol. 40, No. 5. P. 860-867.

[18] Ryabova N.N. complexes of nickel (II) and copper (II) with anions of humic acids and their derivatives // Journal of applied chemistry. 2008. No. 1. P. 75-77.

[19] Budaeva A.D., Zolotoe E.V., Khanturgaeva G.I., Zhambalova B.S. Sorption of copper and zinc from model solutions with humic acids // Сhemistry for sustainable development. 2008. No. 16. P. 143-146.

[20] Janos P., Kormunda M., Novak F., Zivotsky O., Fuotova J., Pilarova V. Multifunctional humate-based magnetic sorbent: Preparation, properties and sorption of Cu (II), phosphates and selected pesticides // React. And Funct. Polym. 2013. Vol. 73, No. 1. P. 46-52.

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Published

2021-05-03