CATALYTIC ACTIVITY OF VANADIUM OXIDE CATALYSTS MODIFIED BY Ti, Sn, Zr OXIDES IN THE PARTIAL OXIDATION OF 4-METHYLPYRIDINE

Authors

  • T. P. MIKHAILOVSKAYA A.B. Bekturov Institute of chemical sciences
  • P. B. VOROBYEV A.B. Bekturov Institute of chemical sciences
  • K.A. Kadirbekov A.B. Bekturov Institute of chemical sciences
  • R. KURMAKYZY A.B. Bekturov Institute of chemical sciences

Keywords:

oxidation, 4-methylpyridine, isonicotinic acid, catalysts

Abstract

The results of catalytic activity of V2O5·МеO2 (Ме = Ti, Sn, Zr) binary catalysts in the partial oxidation of 4-methylpyridine are discussed. It was found that the binary vanadium zirconium oxide catalyst showed the greatest activity in this process. Isonicotinic acid is obtained with the highest yield (57%) at 270 °C and a molar ratio of 4-methylpyridine:О2:Н2О=1:14:110.

References

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Published

2021-05-03