PREPARATION OF SULPHATED FATTY ACID DERIVATIVES OF SPIRULINA OIL

Authors

Keywords:

биомасса, масло Спирулины, аминирование, ацилирование, сульфирование

Abstract

A new sulfonated derivative of Spirulina oil fatty acids was obtained in the work.This derivative is obtained from dry biomass of microalgae in several stages: extraction of lipids from dry biomass, lipid methylation, amination of the formed methyl esters of Spirulina fatty acids, modification of amide with maleic anhydrideand subsequent reaction of the synthesized monoester with sodium bisulfate. The conditions for all stages of the synthesis of the sulfonated derivative were optimized.The initial compounds and reaction products were identified by IR spectroscopy.

 

REFERENCES

[1] Solov’ev A.A., LyaminM.Ya., Koveshnikov L.A., Zayitsev S.I., Kiseleva S.V. Vodo-roslevaya energetika. M.: Nauchnoeizdanie, 1997. 196 p.
[2] Kedik S.A., Yartsev E.I., Dul’tyaeva N.V. Spirulina – pishcha XXI veka. M.: Nauchnoe izdanie, 2006. 166 p.
[3] Komersant’. Nauka 13.05.2020 [elektronnyyresurs]. Rezhim doctupa: https://www.kommersant.ru/doc/4309478 (data obrashcheniya 14.01.2021).
[4] Patent EPV № 023748 В1. Sposob polucheniya atsilamidokarbonovykh kislot / Kharichian B., Van A., Bredreddayin A., Binters D.R., Dayiven P.E.; opubl. 2016.07.29.
[5] Akbar S., Abdurahman N.H., Yunus R.M., Аyaz F.F., Alara O.R. Biosurfactants – a new frontier for social and environmental safety: a mini review // J. Biotech. Res. and Innovat. 2018. No. 2. P. 81-90. https://doi.org/10.1016/j.biori.2018.09.001.
[6] Patent RF № 2 352597 С1. Biorazlagaemaya granulirovannaya poliolefinovaya kompozitsiya I sposob ee polucheniya / PonomarevA.N.; opubl. 2009.04.20.
[7] Patent RF № 2 606 990 С2. Biorazlagaemoe veshchestvo na osnove vozobnovlyaemogo syr’ya / OOO “ProektEkopak”; opubl.2017.01.10.
[8] Organikum. Praktikum po organicheskoyi khimii: v 2-kh tomakh. M.: Mir, 1979. Vol. 2. P. 353-377.
[9] Umerzakova M.B., Donenov B.K., Kainarbaeva Z.N., Kartay A.M., Sarieva R.B. Pilot production of Spirulina biomass and obtaining of novel biodegradable surfactants // Eurasian Chemico-Technological Journal. 2020. Vol. 22, No. 3. P. 219-226. https://doi.org/10.18321/ectj973
[10] Patil H.V., Kulkarni R.D., Mishra S. Synthesis and Characterization of Ethanolamides from Natural Renewable Resources and Utilization in Surfactants Synthesis // Int. J. of Chem. and Chem. Engineer. 2017. Vol. 3, No. 2. P. 69-74.
[11] Ismailov I.T. Sintez I poverkhnostno-aktivnye cvoyistva soleyi sul’fatirovannykh amidov na osnove oleinovoyi kisloty I etanolaminov // Kimya problemlari. 2015. No. 2. P. 144-152.
[12] Moiseeva L.V., Ponomareva L.F. Metody organicheskogo sinteza: galogenirovanie, sul’firovanie. Voronezh: Izd-vo VGU, 2008. 30 p.

Published

2021-05-02