SYNTHESIS OF CALCIUM CHLORIDE FROM TECHNICAL LIME

Authors

  • Umirzak Jussipbekov A.B.Bekturov Institute of Chemical Sciences
  • Raissa Chernyakova A.B.Bekturov Institute of Chemical Sciences
  • Raushan Kaiynbaeva JSC «A.B. Bekturov Institute of Chemical Sciences»
  • Gita Sultanbayeva A.B.Bekturov Institute of Chemical Sciences
  • Irina Kuksina Kazakh National Medical University named after S.D. Asfendiyarov
  • Nazym Kozhabekova JSC «A.B. Bekturov Institute of Chemical Sciences»

Keywords:

calcium chloride, technical lime, well-killing fluid, corrosion rate, corrosivity

Abstract

Introduction. Calcium chloride is a popular product for oil/oil, gas, chemical, chemical-pharmaceutical, forest, construction and other industries. The aim of this work is to synthesize calcium chloride from low-quality limestone, to calculate the material balance of the process of its production and to study the possibility of using CaCI2 in the oil industry.  Methodology: Infrared spectra were filmed on an infrared spectrophotometer in the spectral region 225-4000 cm-1. The basic hydrochloric acid method is selected for producing calcium chloride from technical lime. The synthesis and purification of the CaCI2 solution were carried out according to a known method. Results and discussion. Experiments have shown that calcium chloride enhances the anti-corrosion properties of a seawater well-killing fluid. The highest degree of protection (89.83%) was observed at 35% CaCI2 concentration due to chemical composition.  Introducing CaCI2 into wastewater increases its mineralization and overall hardness, resulting in the formation of a more aggressive environment and an increased corrosion rate. Conclusions: A feasibility study of the process of obtaining pure calcium chloride from technical raw materials was carried out, the material balance of this process was calculated, and it was shown that the cost of the resulting CaCl2 does not exceed the cost of 1 ton of pure CaCl2 on the market of services.

Author Biographies

Umirzak Jussipbekov, A.B.Bekturov Institute of Chemical Sciences

Corresponding Member of the NAS RK, Professor, Doctor of Technical Sciences

Raissa Chernyakova, A.B.Bekturov Institute of Chemical Sciences

Doctor of Technical Sciences, Professor

Raushan Kaiynbaeva, JSC «A.B. Bekturov Institute of Chemical Sciences»

Candidate of Technical Sciences

Gita Sultanbayeva, A.B.Bekturov Institute of Chemical Sciences

Candidate of Technical Sciences

Irina Kuksina , Kazakh National Medical University named after S.D. Asfendiyarov

Master

Nazym Kozhabekova, JSC «A.B. Bekturov Institute of Chemical Sciences»

Candidate of Chemical Sciences

Published

2023-03-30