TERMAL UTILIZATION OF KENDERLYK FIELD SHALES AND SOLID OIL RESIDUE
Keywords:
thermo-catalytic destruction, shale, tar, yield of light fractions, Kenderlyk, organic mass of shaleAbstract
This work presents the results of studies on the joint hydrogenation of the Kendyrlykoil shale and tar to obtain components of motor fuels and the prospects of using the hydrogenation method under low hydrogen pressure.It has been established that the most optimal technological parameters for the process of thermal cracking of tar with oil shale are 425 °C, the process takes 60 minutes and the oil shale added to the tar is 12.0%. When using the Kenderlyk shale under the accepted conditions of thermal cracking, a high yield of light distillates is obtained, calculated on the tar with low coke formation.
References
[1] Copyright certificate 1538504 of the USSR. A method of obtaining liquid products from tar and combustible minerals / Vol-Epstein AB, Galeev R.G., Gorlov E.G. and others. Priority 12.24.87.
[2] Copyright certificate 1540253 of the USSR. A method of obtaining liquid products from tar and fossil fuels / Vol-Epstein A.B., Galeev R.G., Gorlov E.G. et al. Priority 24.12.87.
[3] Copyright certificate 1526207 of the USSR. A method of obtaining liquid products from tar and fossil fuels / Vol-Epstein A.B., Galeev R.G., Gorlov EG. Priority 12.24.87.
[4] Copyright certificate 1594967 of the USSR. A method of producing liquid products from tar / Vol-Epstein AB, Golovin G.S., Gorlov E.G. and others. Priority 07.26.88.
[5] Copyright certificate 1584369 of the USSR. A method of producing liquid products from tar / Vol-Epstein A.B., Gorlov E.G., Golovin G.S. and others. Priority 07.26.88.
[6] Platonov V.V., Vol-Epstein A.B., Klyavina O.A. et al. Study of the structure of compounds of products of thermal dissolution of kerogen-70 from the Baltic oil shale-kukersita // Chemistry of solid fuels. 1982. No. 3. P. 49-52.
[7] Vol-Epstein A.B., Platonov V.V., Shpilberg M.B. et al. Thermal cracking of oil tar // Chemistry of solid fuels. 1990. No. 5. P. 86-91.
[8] Vol-Epstein A.B., Shpilberg M.B., Platonov V.V., Rudensky A.B. Oil shales - hydrogen donors during the thermal dissolution of brown coal of the Kansk-Achinsk basin // Chemistry of solid fuels. 1987. No. 2. P. 75-77.
[9] Dyakova M.K. Transformation of solid fuel into liquid fuel by thermal dissolution / Proceedings of the IGI. Izd-in Academy of Sciences of the USSR. 1948. Vol. 2. P. 445-458.
[10] Dyakova M.K. Production of artificial liquid fuels and chemical products by thermal dissolution of solid fuels // Chemical Processing of Fuels. M.: Publishing House of the Academy of Sciences of the USSR, 1957. P. 261-275.
[11] Vol-Epstein A.B., Shpilberg M.B., Gorlov E.G. Obtaining fuel products by thermal dissolution of enriched Baltic oil shale // Chemistry of solid fuels. 1983. No. 2. P. 59-68.
[12] Vol-Epstein A.B., Shpilberg M.B., Gorlov EG et al. A method for producing liquid products from heavy oil products and solid fossil fuels / Patent No. 2024577. Priority 03.20.92.
[13] Andrienko V.G., Gorlov E.G., Trifonov S.V., Chernukhin A.B. Thermal cracking unit for heavy oil / Patent No. 2058369. Priority 07.17.94.
[14] Bochaver K.Z., Gorlov E.G. Installation of thermal cracking of heavy oil residues / Patent No. 2120462. Priority 10.10.94.
[15] Gorlov E.G., Bochaver K.Z., Stein V.I. Thermal cracking unit for heavy oil residues / Patent No. 2114153. Priority 06.23.97.
[16] Gorlov E.G., Bochaver K.Z., Stein V.I. The method of obtaining liquid products from oil residues / Patent No. 2114895. Priority 06/23/97.
[17] Maloletnev A.S., Kairbekov Zh.K., Yemelyanova V.S., Myltykbaeva Zh.K., Baizhomartov B.B. The deepprocessing of oil residues conjunction with shales // Bulletin of KazNU named after al-Farabi. Ser. chem. 2012. No. 4 (68). P. 22-28.
[18] Kairbekov Zh.K., Emelyanova V.S., Maloletnev A.S., Bayzhomartov B.B. Thermocatalytic hydrogenolysis of oil shale // Bulletin of KazNU named after al-Farabi. Ser. chem. 2012. No. 4 (68). P. 119-125.
[19] Kairbekov Zh.K., Yemelyanova V.S., Baizhomartov B.B. Thermocatalytical processing of coal and shales // Bulletin of KazNU named after al-Farabi.Ser.chem. 2012. No. 4(68). P. 126-133.
[20] Kairbekov Zh.K., Jeldybayeva I.M. Yermoldina Ye.T., Maloletnev A.S. Thermal crac-king of fuel Oil in slate mixture // The Bulletin of the National Academy of Sciences of the Repub-lic of Kazakhstan. ISSN 1991-3494,2018. P. 42-47. https://doi.org/10.32014/2018.2518-1467.5
