PHASE STATE AND RHEOLOGICAL PROPERTIES OF SOLUTIONS OF POLYAMIDE BENZIMIDAZOLE IN DIMETHYLACETAMIDE

Authors

  • A. A. Taltenov Dosmukhamedov Atyrau State University
  • G. К. Shambilova Dosmukhamedov Atyrau State University

Keywords:

poliamidbenzimidazole, a rigid chain polymer, the liquid crystal phase, dimethylacetamide, phase diagrams, rheological properties, solutions of polymer, viscosity

Abstract

The article explores solutions poliamidbenzimidazole used to obtain highstrength heat-resistant fibers and reinforced plastics produced by using precipitants. Investigated rheological properties 5% of the reaction mixtures and solutions poliamidbenzimidazole with polysulfone in DMAА with addition of 3% LiCl, to improve solubility of the polymer. Is constructed part of the phase diagram corresponding to the investigated area of concentration. Shown that viscosimetric and optical methods clearly indicate the existence of a thermodynamic transition in the system poliamidbenzimidazole-DMAА. Also were investigated viscosity properties of mixtures of the solutions poliamidbenzimidazole with PSF in DMAА at different temperatures.

References

[1] Kotomin S.V., Molecular composites and blends polyamidbenzimidazol-polyarilensulfon // VysokomolekulyarnyeComm. Ser. А, 2003, 45, 3, 460-467 (in Rus.).
[2] Iovleva М.М., Banduryan S.I. Some ways to achieve a liquid crystal structure in the systems spinning polymer-solvent // Chem. Fiber. 1995, 2, 9-12 (in Rus.)
[3] Papkov S.P. Rheological properties of abisoptropic poly-(para-benzamide) solutions // J. Polymer Sci.: Polymer Phys Ed. 1973, 12, 9, 1753-1770.
[4] Iovleva М.М. Phasediagramsoffiber-formingpolymers // Chem. Fiber, 2000, 4, 20-25 (in Rus.).
[5] KleninV.I. Thermodynamics of systems with flexible chain polymers / Ed. Saratov State University, 1995 (in Rus.)
[6] Smirnova V.М., Iovleva М.М., Меthods range turbidity and research solutions of fiberforming polymers. М.: NIIТEKHIМ, 1980. 40 p. (in Rus.).
[7] Dreval’ V.E., Malkin A.Ya., Vinogradov G.V., Tager A.A., Effect of the solvent nature on the rheological properties of concentrated solutions of different polymers // Europ. Polymer J. 1973, 9, 1, 85-99.
[8] Dreval’ V.E., Malkin A.Ya., Botvinnik G.O., Approach to genralization of concnetration dependencies of zro-shear viscosities in polymer solutions // J. Polymer Sci.: Polymer Phys Ed. 1973, 11, 6, 1055-1076.
[9] Shambilova G.K. Anomalous temperature dependence of the viscosity of solutions of rigid polymers as a result of the phase transition // Vestnik KazNTU. 2009. 6(76). 182-184 (in Rus.).
[10] Shambilova G.K., Dreval’ V.Е., Kotomin S.V., Kulichikhin V.G. The viscosity and thermal transitions in solutions polyamidbenzimidazole and mixtures there of with polysulfone in dimethylacetamide // Vysokomolekulyarnye Comm. Ser. А, 2010, 52, 1, 3-10 (in Rus.)
[11] Papkov S.P. The gelatinous state of polymers. М.: Chemistry, 1974. 450 p. (in Rus.).
[12] Kuleznev V.N. Association of macromolecules and its effect on the mutual solubility of polymers // Vysokomolekulyarnye. Comm. Ser. B, 1993, 35, 8, 1391-1402 (in Rus.).
[13] Iovleva М.М., Konovalova L.Ya., Negodyaeva G.S., Sokira А.N., Avrorova L.V., Volokhina А.V., Papkov S.P. Structural features of polymers detected by the method of water vapor sorption // Vysokomolekulyarnye. Comm. Ser. B, 1983, 25, 10, 776-778 (in Rus.).
[14] Smirnova V.N., Prozorova G.Е., Iovleva М.М., Papkov S.P., By the estimation of the stiffness of the macromolecules in solution polyamidbenzimidazole // Vysokomolekulyarnye Comm. Ser. B, 1983, 25, 7, 527-529 (in Rus.).
[15] IovlevaМ.М., Physico-chemical aspects of the review of the role and mechanisms of action of lithium chloride in solution of fiber-forming polymers // Chem.fiber. 2001, 3, 10-13 (in Rus.).

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Published

2021-05-03