ALKYLATION OF SODIUM ETHANE-1,2-DIYLDICARBAMODITHIOATE

Abstract

Ssodium ethane-1,2-diyldicarbamodithioate was obtained by the dithiocarbonylation reaction of ethane-1,2-diamine. Then dialkyl ethane-1,2-diyldicarbamodithioates were synthesized by dialkylation of sodium ethane-1,2-diyldicarbamodithioate with 1-bromine(C7, C8, C9, C10 and C12)alkanes in the good and high yields (63-84%). The structure of the reaction products are confirmed by IR, 1H and 13C NMR spectra data.

References

[1] Vizer S.A., Akimbaeva N.O., Erzhanov K.B. Plant growth regulators created in the laboratory of chemistry of physiologically active compounds of the Institute of Chemical Sciences. A.B. Bekturov // Chem. f. Kaz. 2016. N 4. P. 10-45.
[2] Erzhanov K.B., Vizer S.A., Sycheva E.S. Creation of innovative plant growth regulators for a broad spectrum of action. Almaty, 2017. 158 p.
[3] Pat. 22965 Republic of Kazakhstan. IPC8 A01N 39/02, C07C 49/172. N-(3-phenylprop-2yn-1-yl)-N-butyldithiocarbamate, which has a root-forming activity / Erzhanov K.B., Akimbaeva N.O., Saurbaeva B.S., Ermagambetov R.R., Oleichenko S.N., Kampitova G.A.; claimed. 28.10.2009; publ. 15.03.2012, Bul. № 3. 3 p.
[4] I know – the garden of the flowers // Zhailau Journal. The thematic supplement to the magazine AgroAlem. 2009. N 3(3). P. 2-4.
[5] 5. Inn. 25744 Republic of Kazakhstan. IPC8 C08M 39/18. Regulator of growth of seeds of wild medicinal plants / Erzhanov K.B., Akimbaeva N.O., Anuarbekova I.N., Sultanova Z.K., Sotnikova V.V.; claimed. 30/05/2011; publ. 15.05.2012, Bul. № 5.