SORPTION OF HEAVY METAL CATIONS FROM A WATER-SALT SYSTEMBY NATURAL MONTMORILLONITE

Authors

Keywords:

sorption, natural montmorillonite, heavy metals, cations

Abstract

The sorption properties of natural montmorillonite from the Tagan deposit with respect to heavy metal cations were researched on the model system "Mn2+–Co2+– Ni2+–V4+–H2O–montmorillonite". The influence of temperature, duration of the process and concentration of solutions, as well as the norm of the sorbent on the degree of sorption of cations is considered. The optimal conditions for the sorption process (25о С, 30 min, Т:Ж = 1,5:100) have been determined, at which the degree of solution purification is up to 86.36% cations of Co2+, 85.59% of Ni2+, 82.64% of Mn2+ and 52.29% of V4+. The nature of the sorption curves is determined by the nature of the sorbed cation. According to the absorption efficiency of natural montmorillonite, ions are arranged in the following order: Ni2+≥ Co2+> Mn2+> V4+. The results of the conducted studies indicate the possibility of effective use of bentonite clays of the Tagan field in the purification of wastewater from heavy metal cations

References

[1] Somin V.A., Komarova L.F. The use of a sorbent based on bentonite clays and sawdust for water from metal compounds // Polzunov Bulletin. 2009. No. 3. P. 356-360.

[2] Kosov V.I., Ispiryan S.R. The use of peat for the purification of waters polluted by oil products // Water and Ecology: problems and solutions. 2001. No. 4. Р. 41-46.

[3] Jingming G., Xiaoqing W., Xiulan Sh., Shuang Y., Chenlin Y., Xianluo H. Adsorption of heavy metal ions by hierarchically structured magnetite-carbonaceous spheres // Talanta. 2012. Vol. 101, No. 2. P. 45-52.

[4] Tahir S.S., Naseem R. Removal of Cr (III) from Tannery Wastewater by Adsorption onto Bentonite Clay // Separation and Purification Technology. 2007. Vol. 53. P. 312-321.

[5] Dubey S.P., Gopal K. Adsorption of Chromium (VI) on Low Cost Adsorbents Derived from Agricultural Waste Material: A Comparative Study // Journal of Hazardous Materials. 2007. Vol. 145. P. 312-470.

[6] Shakirova V.V., Sadomtseva O.S., Koshkin E.M., Kozhina A.D. Investigation of the sorption processes of some ions of heavy metals on natural materials // Natural sciences. Chemistry. 2016. No. 4(57). Р. 118-124.

[7] Bhattacharyya K.G., Gupta S.S. Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite: A review // Advances in Colloid and Interface Science. 2008. Vol. 140, No. 2. Р. 114-131.

[8] Kanygina O.N., Chetverikova A.G., Strekalovskaya A.D., Varlamova O.V. On the issue of sorption water purification with montmorillonite containing clay // Bulletin of OSU. 2014. No. 9(170). Р. 160-163.

[9] Ramazanov A.Sh., Gamil Kasim Esmail. Purification of wastewater from galvanic production from heavy metals using montmorillonite clay // Ecology and Industry of Russia. 2015. Vol. 19, No. 12. Р. 11-15.

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Published

2021-04-17 — Updated on 2021-04-17