SOME PECULIARITIES OF OBTAINING COMPOSITIONS ON THE BASIS OF ALICYCLIC POLYIMIDE AND NATURAL MINERAL MONTMORILLONITE

Authors

  • M. B. Umerzakova A.B. Bekturov Institute of chemical sciences
  • V. D. Kravtsova A.B. Bekturov Institute of chemical sciences
  • R. M. Iskakov A.B. Bekturov Institute of chemical sciences
  • R. B. Sarieva A.B. Bekturov Institute of chemical sciences
  • Zh. N. Kainarbaeva A.B. Bekturov Institute of chemical sciences

Keywords:

polyimide, montmorillonite, composition, intercalation, complex

Abstract

In this work, an analysis was conducted of research on the production of materials on the basis of alicyclic polyimide with plasticizing additives in the presence of the inorganic filler is montmorillonite by the method of IR-spectroscopy. Installed some of the features of their production, namely, compositions based on alicyclic polyimide with additives alkylated montmorillonite and polyacrylic acid formed intercalated structure. In the ternary compositions of alicyclic polyimide with polyethylene glycol and alkylated montmorillonite, a natural mineral, apparently, forms a complex with terminal groups of polyethylene glycol. The presence of a complex in the ternary composition based on polyimide, polyethylene glycol and montmorillonite, is reflected in the DSC diagram, which manifests itself 2 the specific heat jump corresponding to the polymerpolimer interactions and polymer-low-molecular substance.

References

[1] Sokolova Yu.A., Shabanov S.M., Kadurin L.B., Kalugina E.V. Polymer nanocomposites. Structure. Properties // Plast. mass. 2009. N 3. P. 18-23.
[2] Trofimov A.E., Stepanov I.S., Tankovic A.V. A new approach to the synthesis of organicinorganic nanocomposites // J. prikl. chemistry. 2007. Vol. 81, N 4. P. 627-631.
[3] Napazakov L.Kh., Kozlov G.V., Zaikov G.E. Fractal model of imidazole in the presence of the filler // Plast. mass. 2007. N 12. P. 45-47.
[4] Huang Y., Cu Y. New polyimide – silica organic – inorganic hybrids // J. Appl. Polym. sci. 2003. Vol. 88, N 9. P. 2210-2214.
[5] Cheng C., Cheng H. Effect of reactive channel functional groups and the nanocomposite of nanoscale mesoporouse silica on properties on properties of polyimide // Macromolecules. 2006. Vol. 39, N 22. P. 7583-7590.
[6] Golubeva O., Yudin V.E., Didenko A.L., Svetlichniy V.M. Magnesium and polyimide Nanocomposites based on thermoplastic Gusarov VV-montmorillonite with the structure of silicate nanoparticles // Zh. J. chemistry. 2007. Vol. 81, N 1. P. 106-110.
[7] Baranov A.O., Kotova A.V., Zelenetskiyi A.N., Prut Je.V. When the Impact on the character and the structure of the polymer reaction mixture the reaction property of the chemical smesei // Chemical Success. 1997. Vol. 66, N 10. P. 972-984.
[8] Sariev R.B. With the receipt of a film-based alicyclic additives modified composite polyimide montmorillonite // Hee. jour. Kazakhstan. 2010. N 2. P. 124-133.
[9] Gordon R.A., Ford R. Chemical satellites. M.: Mir, 1976. P. 202.
[10] Encyclopedia of polymers. M.: The Council. Encyclopedia. 1974. Vol. 1. P. 1032.
[11] Pol D., Newman S. Polymer blends. M.: Mir, 1981. Vol. 1, 2. 549, 453 p.
[12] Remy G. Course of inorganic chemistry. M.: Mir, 1972. Vol. 1. 824 p.
[13] Stepicheev A.A., Derevitskaya V.A. fundamentals of the chemistry of macromolecular compounds. M.: Chemistry, 1976. P. 219.
[14] Sarieva R.B., Iskakov R.M., Umerzakova M.B., Batyrbekov E.O., Zhubanov B.A. Composite films on the basis of alicyclic polyimide and natural mineral montmorillonite // Sib. prikl. chemistry. 2011. Vol. 84, vyp. 9. P. 1542-1546.

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Published

2021-05-03