METAL-ORGANIC FRAMEWORKS BASED ENERGY PROPELLANT: EFFECT ON COMBUSTION OF AMMONIUM NITRATE AND MAGNESIUM COMPOSITION

Authors

  • Zh. K. Yelemessova Non-commercial joint-stock company “Al-Farabi Kazakh National university”
  • R. Shen Nanjing University of Science and Technology

Keywords:

Energetic materials, ammonium nitrate, activated carbon, copper oxide, burning rate, activation energy

Abstract

In order to obtain a better understanding of thecombustion characteristics of ammonium nitrate (AN) andcarbon (C) mixtures (AN/C), burning tests and Differential Scanning Calorimetry (DSC) were performed.Ammonium nitrate is widely used in rocket fuels, in explosives and gas generators as an oxidant. However, several major drawbacks have reduced the scope of the application.In order to improve these disadvantages of AN in the composition of composites, energy materials useactivated carbonwith metal oxidesas a metal organic frameworks (MOFs). In addition, the influence of copper oxide on the combustion of compositions and its thermal characteristics was studied.Compositions were combusted at the pressure of 1 MPa, 2 MPa, 3 MPa and 3,5 MPa in the combustion chamber and the burning rates were determined.With the addition of a metal oxide, burning rate has increased for 2‒3 times.The thermal characteristics of compositionswere analyzed using DSC at different heating rates, andthe activation energy of the system was calculated.

References

[1] Chandan Dey, Tanay Kundu, Bishnu P. Biswal, Arijit Mallick* and Rahul Banerjee*. Crystalline metal-organic frameworks (MOFs): synthesis, structure and function ActaCrystallographica Section B. Structural Science, Crystal Engineering and Materials. 2014. Vol. 70. P. 3-10.
[2] Shenghua Li, Yuan Wang, Cai Qi, Xiuxiu Zhao, Jichuan Zhang, Shaowen Zhang and Siping Pang*. 3D Energetic Metal–Organic Frameworks: Synthesis and Properties of High Energy Materials // Angew. Chem. Int. Ed. 2013. Vol. 52. P. 1-6.
[3] Shibashis Halder, Pritam Ghosh, Corrado Rizzoli, Priyabrata Banerjee, Partha Roy. Nitroaromatic explosives detection by a luminescent Cd(II) based metalorganic framework // Journal Polyhedron. 123. 2017. P. 217-225. ISSN 1813-1107 4 2019
[4] Klimova I., Kaljuvee T., Tu¨rn L., Bender V., Trikkel A., Kuusik R. Interactions of ammonium nitrate with different additives // J Therm Anal Calorim. 2011. Vol. 105. P. 13-26.
[5] Sinditskii V.P., Egorshev V.Y., Levshenkov A.I., Serushkin V.V. Ammonium nitrate: combustion mechanism and the role ofadditives // Propellants Explos Pyrotech. 2005. Vol. 30. P. 269-80.
[6] Sudhakar A.O.R., Mathew S. Thermal behaviour of CuO dopedphase-stabilised ammonium nitrate // ThermochimActa. 2006. Vol. 451. P. 5-9.
[7] Canterberry J.B., Schlueter S.S., Adams J.H., Walsh R.K. Gas generating compositions containing phase stabilized ammoniumnit rate. US Patent № 6019861 A. 2000.
[8] Izato Y., Miyake A., Echigoya H. Influence of the physicalproperties of carbon on the thermal decomposition behavior ofammonium nitrate and carbon mixtures //SciTechnolEnergMater. 2009. Vol. 70. P. 101-4.
[9] Miyake A., Izato Y. Thermal decomposition behaviors ofammonium nitrate and carbon mixtures // Int J Energ Mater ChemProp. 2010. Vol. 9. P. 467-75.
[10] Nakamura H., Saeki K., Akiyoshi M., Takahasi K. The reaction ofammonium nitrate with carbon powder // J JpnExplos Soc. 2002. Vol. 63. P. 87-93.
[11] Tomoki Nayaand Makoto Kohga[a]. Burning characteristics of ammonium nitrate-based composite propellants supplemented with MnO2 // Propellants explosive, pyrothec. February 2013. Vol. 38. P. 87-94.
[12] Tomoki Naya, Makoto Kohga. Burning characteristics of ammonium nitrate-based composite propellants supplemented with Fe2O3 // Propellants explosive, pyrothec. August 2013. Issue 4. Vol. 38. P.547-554.

Downloads

Published

2021-05-03