OPTIMIZATION CHROMATOGRAPHY METHOD TO IDENTIFY THE COMPOUNDS ANTHRACENE OIL OF COKE CHEMICAL PRODUCTION

Abstract

Anthracene oil is obtained by vacuum fractionation from coal tar from corporation "ArcelorMittal Temirtau". The product was purified from resinous components by column chromatography. The physicochemical characteristics of anthracene oil from corporation "ArcelorMittal Temirtau" are investigated. Using the methods CMS and GLC analysis components of the hydrogenation products were determined . It is found that use the catalyst of iron-containing composite the carrier of carbon allows to increase the degree of conversion of hydrocarbon derivatives.

References

[1] Akhmetkarimova Zh.S., Muldakhmetov Z.M., Nurkenov O.A., and other // Chemical Journal of Kazakhstan. 2018, 2. 93-99 (in Eng.).
[2] Akhmetkarimova Zh.S. Theory and practice of processing of heavy hydrocarbon raw materials in Central Kazakhstan. Karaganda: "Form plus", 2016. 365 p. (in Rus.).
[3] Patent of the Ministry of Justice of the Republic of Kazakhstan №1863 for the utility model "Method for producing a composite catalyst based on coal sorbent and iron pentacarbonyl" Meyramov M.G., Fazylov S.D., Ordabaeva A.T., Ahmetkarimova Zh.S., Muldahmetov Z. M. 2016 (in Rus.).
[4] Baikenov M.I., Baikenova G.G., Akhmetkarimova Zh.S. // Solid Fuel Chemistry. 2015, 3, 22-28 (in Rus.).
[5] Ordabaeva A.T., Akhmetkarimova Zh.S., Meiramov M.G., Khrupov V.A., Muldakhmetov Zh.H., Dyusekenov A.M., Ma Feng Yun. // Bulletin of the Karaganda university. Chemistry series. 2017, 3(87). 126-130 (in Rus.).
[6] Gudun K.A., Akhmetkarimova Zh.S., Feng-Yung Ma, Baikenov M.I. // Bulletin of the University. 2013, 1(69), 44-48 (in Rus.).
[7] Gagarin S.G., Kirilina T.A., Krichko A.A. // Solid Fuel Chemistry. 1987, 3, 110-114 (in Rus.).
[8] Baikenov M.I., Fengyun Ma, Akhmetkarimova Zh.S. // European Applied Sciences. 2013, 3, 71-73 (in Eng.).
[9] Akhmetkarimova Z.S., Musina G.N., Zhaksybayeva G.Sh. Oil products utilization: theory and practice. Volgograd: Publishing house of the Volgograd Institute of Management, 2018. 120 p. (in Rus.).
[10] Bogzhanova Zh.K., Baikenov M.I., Akhmetkarimova Zh.S., and other. // Bulletin of the University. 2016, 1(69), 40-44 (in Eng.).
[11] Akhmetkarimova Zh.S., Baikenov M.I., Ordabayeva A.T., Muldakhmetov Zh.H., Zhakina A.Kh., Bakirova R.Ye. Hydrogenation of individual compounds (the product of science) // Certificate №009662 of state registration of rights to the object of copyright №2004, 2017 (in Rus.).
[12] Ordabaeva A.T., Akhmetkarimova Z.S., Muldakhmetov Zh.H., Isabekova D.S. Kinetics and thermodynamics of the process of hydrodesulfurization of coal hydrogenation // Sat. scientific tr. "Chemical thermodynamics and kinetics". Tver, 2018. P. 279-280 (in Rus.).
[13] Malyshev V.P. // CUMR. 2009, 4(264), 61-71 (in Rus.).
[14] Akhmetkarimova Zh.S., Muldakhmetov Zh.H., Baikenov M.I., Dyusekenov A.M. // Chemical Journal of Kazakhstan. 2016, 1. 331-336 (in Eng).
[15] Bogzhanova Zh.K., Akhmetkarimova Zh.S., Muldakhmetov Z.M., and other // News of NAS RK. 2016, 2, 23-29 (in Kaz.).
[16] Lipovich V.G., Kalabin G.A., Kalechits I.V. // Chemistry and processing of coal. M.: Chemistry, 1988, 336 p. (in Rus.).
[17] Borah D., Barua M., Baruah M. K. // Fuel Process. Technol. 2005, 86.977-993 (in Eng.).
[18] Karimova L., Karimov R. Equilibrium-kinetic analysis. M.: Lap Lambert Academic Publishing, 2014, 65 p. (in Rus.).
[19] Ctromberg A.G., Semchenko D.P. Physical chemistry. M.: Higher School, 1988. 315 p. (in Russ).
[20] Zamanov V.V., Krichko A.A., Ozerenko A.A., Frosin S.B. // Solid fuel chemistry. 2005, 42, 67-70 (in Rus.).