The translation method predicted phase equilibria on geometric images of the system K,Mg,Ca||SO4,Cl-H2O at 00 C. It was found that at 0 °C the studied system is characterized by the presence of 6 invariant points, 18 monovariant curves and 15 divariant fields. Based on the data obtained, a diagram of the phase complex of the K,Mg,Ca||SO4,Cl-H2O at 0°C and fragmented by divariant fields, as well as crystallization fields of individual equilibrium solid phases, was constructed.
References
[1] Goroshenko Ya.G. Physicochemical analysis of homogeneous and heterogeneous systems. Kiev: Nauk. Dumka. 1978. 490 p.
[2] Goroshenko Ya.G. Mass-centric methud of imaging multicomponent systems. Kiev: Nauk. Dumka. 1982. 264 p.
[3] Soliev L. Prediction of the structure of phase equilibrium diagrams of multicomponent water-salt systems by the translation method. M.: 1987. 28 p. Dep. VINITI AN SSSR 20.12.1987. No. 8990-В87.
[4] Kurnakov N.S. // Dokl. Academy of Sciences of the USSS. 1939. Vol. 25, No. 5. 384 p.
[5] Kurnakov N.S. Introduction to physical and chemical analysis. M.; L.: Publishing house of
the Academy of Sciences of the USSR. 1940. 562 p.
[6] Goroshenko Ya.G., Soliev L. // Journal of Inorganic Chemistry. 1987. Vol. 32, No. 7. P. 1676.
[7] Handbook of experimental data on the solubility of multicomponent water-salt systems. SPb.: Khimizdat, 2004. Vol. II, book 1-2. 1248 p.
[8] Soliev L. // Journal of Inorganic Chemistry. 1988. Vol. 33, No. 5. P. 1305.