THE THERMAL PROPERTIES OF TRIPLE COMPOSITIONS BASED ON ALICYCLIC POLYIMIDE POLYMER ADDITIVES
Keywords:
polycyclic polyimide, polyacrylamide, polyethylene glycol, thermal properties, TGA and DSC analysisAbstract
The basic physical and chemical properties of new triple compositions based on polycyclic polyimide with additives of polyacrylamide and polyethylene glycol were determined by TGA and DSC analysis. It was found that for the optimal ratio of plasticizing additives in polyimide there is a good compatibility of the mixture components and there is an improvement of 36°C thermal and 2.4 times increase in strength properties, while the elasticity of the composite material as a whole does not deteriorate.
References
[1] Kravchenko T.P., Ermakov S.N., Kerber M.L., Kosgyagina V.A. Nauchno-tekhnicheskie problemy polucheniya kompozicionnyh materialov na osnove konstrukcionnyh termoplastov // Plasticheskie massy. 2010. N 10. P. 32-36.
[2] Meleshko T.K. Elektroprovodyashchie plenkoobrazuyushchie kompozicii na osnove smesi polianilina i poliimida // Vysokomolek. soed. Ser. A. 2009. Vol. 51, N 3. P. 447-450.
[3] Krut'ko EH.T., Prokopchuk N.R. Perspektivnye puti sozdaniya novyh termostojkih materialov na osnove poliimidov // Himiya i tekhnologiya organicheskih veshchestv, materialov i izdelij. 2013. N 4. P. 145-149.
[4] Zhubanov B.A., Kravtsova V.D., Bekmagametova K.H., Ahmettaev D.D. Elektricheskie svojstva aliciklicheskih poliimidov. Almaty: Nauchnoe izdanie, TOO «Print-S», 2010. 225 p.
[5] Kravtsova V.D., Umerzakova M.B., Iskakov R.M., Korobova N. Electrical properties of fluorocontaining alicyclic polyimides // J. Chem. and Chem. Engineer. 2015. Vol. 9, N 1. P. 31-37.
[6] Volynskiy A.L., Bakeev N.F. Novyy podkhod k sozdaniyu nanokompozitov s polimernoyi matritseyi // Vysokomolek. soed. 2011. Vol. 53, N 7. P. 1203-1216.
[7] Chvalun S.N. Polymer nanocomposites // Nature. 2000. N 7. P. 1-13.
[8] Mehnson Dzh., Spering L. Polimernye smesi i kompozity. M.: Himiya, 1979. 439 p.
[9] Bogdanov V.V., Torner R.V. Smeshenie polimerov. M.: Himiya, 1990. 198 p.
[10] Zhubanov B.A., Umerzakova M.B., Kravtsova V.D., Iskakov R.M., Sarieva R.B. Polymeric composites based on alicyclic polyimide and Poly(ethylene glycol) // Russ. J. Appl. Chem. 2013. Vol. 86, N 10. P. 1605-1609.
[11] Innovacionnyy patent RK № 20266. Polimernaya kompoziciya dlya polucheniya plenki na osnove aliciklicheskogo poliimida i poliakrilamida / Zhubanov B.A., Umerzakova M. B., Kravtsova V. D., Iskakov R. M., Sarieva R.B.; opubl. 15.12.2014, B. № 12.
[12] Zhubanov B.A., Kravtsova V.D., Almabekov O.A., Bekmagambetova K.H. Galogensoderzhashchie poliimidy. Almaty: TOO «Evero», 2004. P. 218.
[13] Zhubanov B.A., Arhipova I.A., Almabekov O.A. Novye termostojkie geterociklicheskie polimery. Alma-Ata: Nauka, 1979. 252 p.
[14] Zhubanov B.A., Kozhabekov S.S., Almabekov O.A., Kravtsova V.D., Kozhabekova T.K. Termicheskaya i termookislitel'naya destrukciya poliimidov arilaliciklicheskogo stroeniya // Studies of Macromolecular Compounds: Works IKhN AN KazSSR. Alma-Ata, 1990. P. 37-62.
[15] Rabek YA. Eksperimental'nye metody v himii polimerov. M.: Mir, 1983. Vol. 1. 381 p.; Vol. 2. 479 p.
[16] Pol D., N'yumen S. Polimernye smesi. M.: Mir, 1981. Vol. 1. 549 p.; Vol. 2. 450 p.
[17] Kratkaya himicheskaya enciklopediya. Vol. 4. M.: Sov. enciklopediya, 1965. P. 96, 102.
[18] Bekturov E.A., Bimendina L.A. Interpolimernye kompleksy. Alma-Ata: Nauka, 1977. 263 p.
[19] Enciklopediya polimerov. Vol. 1. M.: Sov. enciklopediya, 1972. P. 30; Vol. 2. 1974. P. 430.
