CARBONYLATION OF α-OLEFINES WITH CARBON MONOXIDE AND ALCOHOLS IN THE PRESENCE OF PALLADIUM PHOSPHINE COMPLEXES

Abstract

The data on the use of homogeneous metal complex catalysts in organic synthesis, the use of metal complex catalysts with phosphorus-containing ligands in the catalytic hydroalkoxycarbonylation of carbon monoxide olefins and mono(poly)atomic alcohols in free phosphine complexes of palladium. Developed new, effective and environmentally friendly ways to obtain almost any valuable carboxylic acids. Oxygen reactions are associated with the release of normal and heterogeneous structures with low carbon monoxide pressure (≤ 20 atm) in two- and three-component systems based on PdCl2 and Pd(Acac)2, PdCl2(PPh3)2, free PdCl2 systems, and free ligand (PPh3) and stabilizer (TsOH) as promoter. According to the research results, the most effective catalytic activity in the studied reactions is only three-component systems PdCl2-PPh3-TsOH, PdCl2(PPh3)2-PPh3TsOH, Pd(Acac)2-PPh3-TsOH and Pd(PPh3)4-PPh3-TsOH. The effect of various reaction conditions on the course of the process and on the yield of the target products was studied.

References

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