ARYLALICYCLIC COPOLYIMIDES AND METAL-CONTAINING COMPOSITIONS BASED ON THEM

Authors

  • M. B. Umerzakova A.B. Bekturov Institute of chemical sciences
  • V. D. Kravtsova A.B. Bekturov Institute of chemical sciences
  • R. B. Sarieva A.B. Bekturov Institute of chemical sciences

Keywords:

copolyimide, metal-containing composition, viscosity, polymer film, thermal stability

Abstract

New copolyimides were obtained on the basis of tricyclodecentetracarboxylic and diphenyloxydtetracarboxylic acid dianhydrides with diaminodiphenyl ether with a different ratio of dianhydrides and metal compositions based on them. Optimal conditions for synthesis of the copolymers were selected, their basic properties were studied. It is shown that their solutions in methylpyrrolidone are stable for a long time. The copolyimides obtained and their metal-containing compositions are characterized by higher thermal stability comparatively with alicyclic polyimide and greater stability when exposed to alkaline media as comparatively with polyimide of aromatic structure.

References

[1] Matsumoto Т., Mikami D., Hashimoto T., Kaise M., Takahashi R., Kawabata Sh. Alicyclic polyimides – a colorless and thermally stable polymer for opto-electronic devices // J. of Physics: conf. ser. 2009. Vol. 187. P. 3-11.
[2] Cosutchi A.I., Nica S.-L., Hulubei С., Homocianu M., Ioan S. Effects of the aliphatic/aromatic structure on the miscibility, thermal, optical, and rheological properties of some polyimide blends // Polym. Eng. Sci. 2012. Vol. 52, N 7. P. 1429-1439.
[3] Zhubanov B.A., Kravtsova V.D., Mukhamedova R.F., Bekmagambetova K.Kh. New polymer systems based on alicyclic polyimides // Russ. J. Appl. Chem. 2006. Vol. 79, N 11. P. 1869-1874.
[4] Hulubei C., Popovici D. Novel polyimides containing alicyclic units. Synthesis and characterization // Rev. Roum. Chim. 2011. Vol. 56. P. 209-215.
[5] Zhubanov B.A., Kravtsova V.D., Umerzakova М.B., Iskakov R.M., Sarieva R.B, Alpyspaeva B. E. Compositions on the basis of alicyclic polyimide with polyurethane // Khim. zhur. Kazakhstana. 2014. N 2. P. 54-59.
[6] Krutko E.T., Prokupchuk N.R., Globa A.I. Khimicheskaya modifikatsiya polipiromellitimida // Polimernye materialy i tekhnologii. 2017. Vol. 3, N 1. P. 33-46.
[7] Novakov I.A., Orlinson B.S., Brunilin R.V., Potaenkova E.A. Soluble polyimides and copolyimides with increased hydrolytic stability that are based on [(2-amino)- and (2-aminomethyl)bicyclo[2.2.1]hept-3-yl]anilines // Polymer Science. Ser. B. 2010. Vol. 52, N 9-10. P. 609-613.
[8] Okabe Т., Morikawa A. Synthesis of polyimides from 3,3'-dihydroxybenzidine and conversion to polybenzoxazoles // High Perform. Polym. 2008. Vol. 20, N 1. P. 53-66.
[9] Lan Ying Jiang, Yan Wang, Tai-Shung Chunga, Xiang Yi Qiao, Jun-Yih La. Polyimides membranes for pervaporation and biofuels separation // Progress in Polymer Science. 2009. Vol. 34. P. 1135-1160.
[10] Krutko E.T., Prokupchuk N.R. Perspektivnye puti sozdaniya novykh termostoikikh materialov na osnove poliimidov // Khimiya i tekhnologiya organicheskikh veshchestv, materialov i izdeleyi: trudy BGTU. 2013. N 4. P. 145-149.
[11] Kardash M.M., Artemenko S.E. Fiziko-khimicheskie osobennosti protsessa polucheniya PKM pri polikondesatsionnom napolnenii // Plast. Massy. 2008. N 1. P. 6-8.
[12] Yudin V.E., Bugrov A.N., Didenko A.L., Smirnova V.E., Gofman I.V., Kononova S.V., Kremnev R.V., Popova E.N., Svetlichnyi V.M., Kudryavtsev V.V. // Polym. Sci. Ser. B. 2014.
Vol. 56, N 6. P. 859-866.
[13] Monomery dlya polikondencatsii / Perevod s angl. Vygodskogo Ya.S. pod red. Korshaka V.V. M.: Mir, 1976.
[14] Kravtsova V.D., Umerzakova M., Iskakov R., Korobova N. Electrical properties of fluorocontaining alicyclic polyimides // J. Chem. and Chem. Engin. 2015. Vol. 9, N 1. P. 31-37.
[15] Blythe E.R., Blur D. Electrical Properties of Polymers. London-N.Y.: Cambridge Univ.
Press, 2005.
[16] Zhubanov B.A., Umerzakova M.B., Kravtsova V.D., Iskakov R.M., Sarieva R.B. Polymeric composites based on alicyclic polyimide and Poly(ethylene glycol) // Russ. J. Appl. Chem. 2013. Vol. 86, N 10. P. 1605-1609.
[17] Kudo K., Yoshizawa T., Hamada T., Li J., Sakamoto S., Shiraishi S. One-pot synthesis of an alternating copolyimide based on regioselective reaction of a non-symmetrical alicyclic dianhydride // Macromol. Rapid Commun. 2006. Vol. 27, N 17. P. 1430-1436.
[18] Yanovsky Yu.G., Semenov N.A., Sidorov G.Ya., Karnet Yu.N. Smart materials with electrically controlled properties electrorheological suspernsions with a nanosized polymeric dispersed phase. Part 2. Experimental investigation of electrorheological suspensions based on polyimides // Nanomechanics Science and Technology: An Int. J. 2012. Vol. 3. P. 239-281.
[19] Brudanov A.M. Prakticheskoe primenenie smart-materialov и smart-konstruktsiy // Molodoyi uchehyy. 2015. N 24. P. 101-104.
[20] Kuznetsov A.A., Shlyakhtin O.A., Brusentsov N.A., Kuznetsov O.A. Smart Mediators for Self-Controlled Inductive Heating // J. European Cells and Material. 2002. N 3(2). Р. 75-77.

Published

2021-05-03