COMPARISON OF THE SORPTION PROPERTIES OF THE INDIVIDUAL POLYMER HYDROGELS OF POLY(ACRYLIC) AND POLY(METHACRYLIC) ACIDS IN RELATION TO RARE EARTH METALS IONS
Keywords:
hydrogels, polyacrylic acid, polymethacrylic acid, sorption, ions, , rare earth metalsAbstract
The process of rare earth elements ions sorption (lanthanum, cerium, neodymium, samarium) by individual hydrogels of poly(acrylic) and poly(methacrylic) acids was studied. The degree of lanthanum, cerium, neodymium, samariumions sorption by individual PAA hydrogel reached maximum values (67.71, 63.33, 61.60, 66.28%, respectively) after 48 hours of interaction. The degree of lanthanum, cerium, neodymium, samarium ions sorption by individual PMAA hydrogel reached maximum values (66.28, 60.33, 57.90, 64.79%, respectively) after 48 hours of interaction. It is shown that despite the fact that polymer hydrogels are weak electrolytes, macromolecules interact with the ions present in solutions. Sorption of lanthanum, cerium, neodymium and samarium ions occurs by attaching them to oppositely charged carboxylate anion.
References
[1] Kudrin V.S., Chistov L.E. Sostojanie mineral'no-syr'evoj bazy redkozemel'nyh metallov, perspektivy ee razvitija i osvoenija // Mineral'nye resursy Rossii. 1996. N 15. P. 6-12.
[2] Karenov R.S. Problemy formirovanija rynka redkih i redkozemel'nyh metallov v Kazahstane // Vestnik Karagandinskogo gosudarstvennogo universiteta. Ser. Jekonomika. 2007.
[3] Jumadilov T.K., Abilov Zh.A., Kaldayeva S.S., Himersen H., Kondaurov R.G. Ionic equillibrium and conformational state in intergel system based on polyacrylic acid and poly-4vinylpyridine hydrogels // Journal of Chemical Engineering and Chemistry Research. 2014. Vol. 1. P. 253-261.
[4] Jumadilov T.K., Kondaurov R.G., Khakimzhanov S.A., Himersen H., Yeskaliyeva G.K. Influence of initial state of hydrogels on self-organization of polymer networks of polymethacrylic acid and poly-4-vinylpyridine at their remote interaction in an aqueous medium // Chemical Journal of Kazakhstan. 2018. N 1. P. 42-48.